The understanding of the combustion performance of blends is important in determining the
economical and environmental benefit of blending. The combustion performance of a blend dictates
the level of carbon in the ash, with high carbon-in-ash equating to energy losses and increased ash
disposal costs. Emissions of NOx, SOx, CO2 and particulates are also influenced by blend
composition.
This brief review is based on CoalTech's report examining the performance of thermal coal blends
for the Queensland Government.
The combustion performance of a coal blend is more complex than that of a single coal because it
is not only dependant on the combustion performance of each component coal but also on possible
interactions between coals. This interaction between coals first occurs:
- in the milling of the blend if there are large differences in the hardness of each coal then
there is potential for large differences in the size distribution of the component coals which
will influence flame stability, burnout and possible NOx formation.
- within the burner flame the volatile release from the different blend components will impact
flame temperature and therefore can influence flame stability, char reactivity and NOx
formation.
CoalTech's milling and combustion model shows how size distribution of some component coals
can impact on burnout performance. For blends with similar milling behaviour the burnout of blends
is additive and can be determined from the burnout performance of the component coals. When
the milling performance of component coals differs significantly then there will be preferential
grinding of the softer coal leading to a finer size distribution for that coal. Usually the softer coal is
of higher rank, lower volatile content and poorer burnout performance. The preferential grinding of
the softer, lower volatile coals does allow, depending on the coal, up to 30% of the lower volatile
coal to be used in blends that will have acceptable burnouts similar to the higher volatile coal.
The model also indicates that when these higher rank coals are used in proportions greater than
50% the burnout can be similar or worse than the higher rank coal if it was burnt unblended.
As the temperature at which the blend burns increases, due to higher load, burner and boiler
design ,the impact of differential grinding decreases and burnout of the blend approaches a linear
relationship to the burnout of the component coals.
The simple model developed does not allow for any influence of different maceral types. There is
some evidence that fragmentation will increase the burnout of some lower volatile coals with high
vitrinite content. This fragmentation can be increased when the heating rate within the flame is
increased by the addition of a higher volatile coal and there is sufficient oxygen in the flame to
oxidise the char surface.
Flame stability of a blend is greatly enhanced when only small amounts of a Surat Basin coal is
included in a blend. This is due to the high hydrogen content of this per- hydrous coal which
contributes to a high energy release within the flame.
Based on the findings in this report, lower volatile Bowen Basin coals that are now excluded from
the international thermal coal market could be used in thermal coal blends in proportions of up to
30% without unduly impacting on combustion performance.
The early release of coal nitrogen within the fuel rich region of a flame is the key to the minimising
of
NOx emissions. Second generation low-NOx burners generate rapid heating and high
temperatures at the centre of the fuel-rich flame, which promotes the devolatilisation of the coal and
early release of fuel nitrogen leading to lower NOx emissions, better flame stability and carbon
burnout.
Coals with high volatile content and low nitrogen content produce very low NOx emissions. The
addition of these coals to a thermal coal blend will significantly reduce NOx emissions. It has been
demonstrated in full-scale burner tests that the medium and low volatile coals of the Bowen Basin
can be fired in second generation low-NOx burners with acceptable NOxemissions.
The general application of correlations for the prediction of
slagging and fouling or electrostatic
precipitator behaviour for a wide range of coals, based on ash analysis, needs to be treated with a
degree of caution. This is because it is the amount, size and type of minerals in the coal and
surface composition of the fly ash that iare important not the bulk composition. A wide range of
slagging and fouling indices are given in this report, their use will only indicate potential problems.
The correlation used in the CoalTech report on blending between ash properties and the
performance of an ESP does give a reasonable estimate for the outlet dust loading for most single
coals. But this correlation failed to predict the very good ESP performance of Surat Basin coals
which resulted in low particulate emissions. When Surat Basin coals are used in blends with a
coal of poor ESP performance there is an improvement that is far greater than if ESP performance
was additive.