ACARP Project Number: C13066
Published: August 08
Philip Bennett, Daniel Rigg
Extended
Abstract
The aim of this project is was to develop a
simple tool that allows the determination of the fusibility of
inertinite in Australian coals. The first step in determining
the fusible inertinite component is to convert the petrographic
analysis to a mass basis. This requires relationships between the
rank of the coal and the densities of the maceral groups. To
determine these relationships eight coals were subjected to float
sink analysis using eight liquid densities. In determining the
densities of the maceral groups assumptions must be made relating
to the mineral (vol %) and the ash content of the coal. Using
mineralogical data determined by QEMSCAN on selected float sink
samples of the each coal it was possible to determine a
relationship between the ash (%d) with minerals (mass %) and also
with minerals (vol %). Using minimisation techniques the best
estimates were derived for the densities of the vitrinite and
inertinite of the eight coals. Due to the small or zero amount of
liptinite in the coals it was not possible to determine the density
of liptinite.
The calculated densities of vitrinite and
inertinite for the eight coals showed very similar relationships
with rank (carbon %daf) as those given by van Krevelen (1961). It
is recommended the relationships derived by curve fit to the data
of van Krevelen be used to determine the density of the maceral
groups.
The next step in determining the fusible
inertinite is to estimate the loss of volatile components during
carbonisation. Degassing experiments were conducted in small cast
iron pots (mini pots) to determine the yield of coke and to prepare
coke samples for coke microtexture analysis. A mini pot was packed
with 110g of coal to a bulk density of 900 kg/m3. Two mini pots
were prepared for each of the four float sink fractions of the
eight coals. Ten mini pots were then place into a 7kg bench scale
oven for carbonisation.
The mini pot coke tests shows that more of the
inertinite can be fused when in close proximity to vitrinite
(finely crushed coal packed densely and then coked).
As the mini pot coke results have a higher coke
yield and higher fused inertinite than would be normally found for
pilot scale data it was decided to extend this project to include
the examination of the data from ACARP project C12057 (Bennett et
al., 2008). In project C12057 twelve coals were coked in a pilot
scale oven and coke microtexture analysis was conducted on the
cokes.
There is good agreement between the calculated
coke yields and the actual pilot scale coke yield using the coke
yield determinations approaches given above. The predicted coke
yield based on the pilot scale correlation and the measured
volatile matter is, as expected, very good. The two predicted coke
yields using petrographic analysis (Diessel & Wolff-Fischer and
fitted relationships) do vary slightly from the actual results but
the variation is different for different coals, indicating the
variation is not just due to errors relating to the petrographic
analyses.
All pilot oven cokes show that more than 50% of
the semifusinite is fusible with some having more than 90% of the
semifusinite fusible.
Several different methods for the prediction of
fused carbon in coke were evaluated using the pilot scale
data.
A good prediction of fused carbon includes the
vitrinite and liptinite in the coke and also the amount of
inertinite with a reflectance close to the Romax of the vitrinite.
Though there is still an influence of how the inertinite is
distributed in the coal matrix - more inertinite in the
microlithotype inertite then the less fused carbon in the
coke.
The minerals in the coal do seem to have a slight
influence on fused carbon when dispersed evenly through the coal as
shown by the mini pot coke tests. This influence is not seen in the
pilot scale tests. This may be due to the minerals being mostly
associated with the inertinite and that the large inertinite pieces
do not play a large role in the formation of fused carbon.